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Preheat oven to 325 F.
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Generously grease and flour (2) 9-inch round cake pans. Set aside.
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In a medium bowl, whisk together flour, baking soda, baking powder, cocoa powder and salt. Set aside.
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In a large bowl, combine the sugar and vegetable oil.
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Mix in the eggs, buttermilk, vanilla and red food coloring until combined.
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Stir in the coffee and white vinegar.
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Combine the wet ingredients with the dry ingredients a little at time, mixing after each addition, just until combined. (Batter will be thin)
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Pour the batter evenly into each pan.
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Bake in the middle rack for 30-40 minutes or until a toothpick inserted in center comes out with moist crumbs clinging to it. Do not over bake as cake will continue to cook as it cools.
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Let pans cool on a cooling rack until the pans are warm to the touch.
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Slide a knife or offset spatula around the inside of the pans to loosen the cake from the pan.
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Gently remove the cakes from the pan and let them finish cooling. (The warm cake will be very delicate)
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Frost the cake with cream cheese frosting when the cakes have cooled completely.